Pondscum said:
Dimethyl silicone is one "bad" silicone which should not be used on Rubber/Vinyl/Plastic because it migrates to and interferes with the plasticizers in those materials. I think this is the bad rap which led people to believe all silicones were bad regardless of which ones they were or what they were used on. There are lots of other silicone compounds that work very well in dozens of automotive applications, including Rubber/Vinyl/Plastic protectant products.
:xyxthumbs
Silicone:
The Good: Polydimethylsiloxane (PDS) is water based, amino functional polymer that doesn't migrate (dry out) the plasticizers from materials, has less UV radiation absorption and dust attraction properties.
Chemists use water-in-oil emulsions, to reduce emulsion particle size, to stabilize emulsions, and to improve spreading and coverage of wax products.
Most modern silicone formulas are water soluble (no petroleum), and are completely inert. The best way to describe most forms of silicone is to think of it as a man-made wax ester. Silicone is created by the reaction generated when you combine fatty acids with Polydimethylsiloxane
The Bad: Dimethyl is derived from Aromatic hydrocarbons (petroleum ) distillates, which are environmentally unsound and give a slick, oily finish, which attracts dust and dirt. It also causes rubber compounds along with sun iteration to remove the micro-wax in tyres as well as its carbon black (it's what gives tyres their colour) they are often mislabelled as modem /synthetic polymers by manufactures.
The Ugly: Silicone is an active ingredient in sun UV amplification. As a low quality silicone dressing evaporates away, the silicone oil is left behind, the sun then amplifies these residues, and the drying process is accelerated.
All this causes rubber, EDPM, vinyl and plastics to dry out, which turns them grey or brown, losing their flexibility and prematurely fail. Water-based dressings do not contain oils or petroleum distillates and provide a non- greasy, natural looking satin finish.
For a Few Dollars More: Hydrocarbon (petroleum) distillates can be further purified, re-distilled, reacted and combined with various other chemicals to produce a wide range of environmentally safe and useful silicone products. In conclusion, to group all silicones into one category and label them harmful, environmentally unsound or dangerous is both unscientific and without foundation.
JonM