Yes and no. Polycharger is a catalyzer and will shorten cure times. However, as most sealant manufactures have discovered, it is near impossible to catalyzed a sealant to the point of instant cure times and maintain a shelf life. The catalyzing agents acts to cure the sealant as it sits on the shelf, for a lack of a better term. Blackfire has a precise amount of polycharger blended to into the formula, enough to drastically improve the performance, while having no negative effect on shelf life or application.
That said you can still 'amp' the product by adding additional polycharger into an ounce or so Blackfire directly before application. This is will shorten cure times significant and may increase the shine further. Keep in mind that the amount that you mixed with additional polycharger should be discarded after 24 hours or so.
Alternatively, if you have an older bottle of Wet Diamond (pre polycharger) you can add polycharger to that prior to application and receive many, although not near all, the benefits of the new formula. The new formula will still outperform it slight do to other changes in the base, but you will notice better performance none-the-less.