I came across this a while ago and saved it if I needed it. Haven't had the chance to try it but will share it with you guys if it's worth anything:
Concrete Spots:
Calcified water spots on paint and glass, water and concrete spots are pretty much the same chemically - calcium carbonate, with the concrete being cross-linked with water
Methodology
•Apply 1:1 ratio water with distilled White Vinegar solution, and using a spray bottle, spray that mixture on the spots and let them "soak." Then rinse with water and repeat as necessary.
•If the ambient temperature water/vinegar mix does not work, warm (100-120 degrees) 100% distilled White Vinegar, saturate a clean kitchen sponge with pure vinegar and hold the sponge over the concrete spots for a few minutes.
•If the above do not remove them try equal parts distilled water, isopropyl alcohol and distilled white vinegar. The acid in the vinegar will help etch and dissolve the concrete.
•Rinse the area thoroughly with water after the vinegar and then reapply wax or sealant to that area.