Biochem major here. pH is complex, but some are interested, so I`ll try to explain acid based reactions. pH is part of the equation in predicting how an acid (or base) will react, but of at least equal importance are molarity (concentration), whether it`s buffered (a buffer is something you add to a solution to help it maintain it`s pH when other chemicals act upon it, generally more important with weak acid or bases), and contact (you can pour a gallon of anything on your car, but most of it falls off the car, and only the micro-layer touching the clear coat can react with the clear coat. Or LSP).
Electricity analogy - pH is the "voltage," molarity/buffer/contact/volume is the "amperage." You need both to do damage. I would argue that any car shampoo has neither.
Just a quick note about all of the above. Acid (or base) is finite. Once it reacts, it`s gone. So for an effective acid reaction, you either need lots of it (molarity) or you need to continually replenish it (buffer and contact/amount).
Then there is the issue of what acid works on. Acids react better on inorganics than organics. In our world, inorganics are metals. Organics are things petroleum based - clear coat, sealants, waxes. Vinegar works well on water spots because they are inorganic - the residue left over by hard water (calcium, iron, magnesium, i.e. metals). However, vinegar would take forever to do much damage to an LSP. This is a complicated discussion also, but has to do with the same forces at work whereby water will dissolve road salt (inorganic metal), but won`t dissolve your LSP (organic).
I would go further than Dr. G and say that anything pH 4-10 is essentially neutral. Even then, something like vinegar has a pH of 2.4, does that scald your skin? No. pH 2.4 isn`t that crazy, plus vinegar has low molarity, is unbuffered, and not enough is going to stick to your skin to bother you. If you hold your hand in a large vat of vinegar, over time, you would start to feel some irritation. But you can`t mimic that situation with your car, and your clear coat or LSP is going to be more impervious to pH than your skin.
So, you wash your car. Even a non-"pH balanced" shampoo has nothing going for it to disturb your clear coat or LSP. It has essentially neutral pH (by my definition), it has low molarity, it`s not buffered, very little stays on your car, and what stays on your car is not there for long. Plus, acids don`t react well with organics to begin with.
Anyway, I warned you it was complex, but in the end, this is why I could not care less what the pH of my shampoo is. If it`s not acidic or basic enough to burn my skin, then the pH is negligible as it concerns my LSP or clear coat. As Dr. G mentioned, the surfactants in shampoos are going to dissolve LSPs far more than any weak acids or bases.
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