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togwt
08-01-2011, 06:45 AM
Nanotechnology coatings



Some of the materials and technologies that have changed detailing forever; Polymer sealants, Detailers clay, Microfiber towels, Nanotechnology coatings, Polishes containing nanotechnology ceramic micro-particulate, diminishing abrasives and Full body vinyl wraps



Probably the greatest impact has come from the use of Nanotechnology coatings, which have completely changed the landscape of the detailing industry. Products like Zaino, Collinite, and etc used to be the best protection available but nanotechnology (AQuartz) or a reactive polymer resin coatings (Opti-Coatâ„¢ ) that offer greatly extended durability, scratch resistance and protection from the elements that can be measured in seasons or years, as opposed to others



For many years (twenty plus) my polymer sealant of choice was an acrylic polymer (Klasse) I then converted to a polymer sealant (Zaino) and used it for approx fifteen years, but automotive sealants and coatings have evolved immensely over the last five years or so and have changed paint protection to an inordinate degree



Paint sealants compared to Coatings



Paint sealants are synthetic products designed for long-term paint protection and easy application. They are composed mainly of amino functional polymers, which last longer than any natural wax and are highly resistant to the elements. Synthetic liquid waxes are another way of describing paint sealants. The main benefit of a paint sealant is their durability compared to a wax, polymer-based sealants will last anywhere from 3 to 6 months.



A coating is applied to a clean surface and are capable of `film build`, that is to say a measurable thickness, that surface takes on properties that are virtually identical to hardened glass. It is chemically inert and will not react with the base material. In other words, dirt will not bond to the treated surface, thereby reducing soiling and organic staining. Acid rain and other chemical compounds easily wash off, significantly reducing the hydroscopic nature of surfaces exposed to industrial or environmental pollution.



Paint Surfaces



Automotive paint surfaces are porous and can hold up to a pint of water after washing, so ensure that the surface has been thoroughly dried before the application of a sealent or coating. A paint surface comprise contain microscopic peaks and valleys, much like the profile of a mountain range. These irregularities are known as capillary structures; there may be millions of these defects per square inch. Contaminants such as fine dirt, minerals, and pollutants are drawn into the voids where they are extremely hard to remove.



The filling of the capillary structures with nanoparticles produces a hydrophobic surface. (A hydrophobic surface is one that repels moisture.) In contrast, a hydrophilic surface is one that absorbs moisture. The potential of a surface to absorb or repel moisture is based on many factors, including: temperature, relative humidity, material ````geneity, and static electricity. Surface roughness is also a major factor; the rougher the surface, the higher the spreading rate or attraction for water. The smoother the surface, the more repellent it is to moisture.



The significance of a nano-coating is its small particle size that can form a very tight bond with the surface of most materials; including glass, paint, plastic, rubber, aluminium, chrome, stainless steel and fabrics, will have surface imperfections i.e. micro-fissures when viewed under high magnification. These undulations allow a nano-coating polymer to form a tight molecular bond (much like a printers ink when poured over paper that has writing indentations on it) with the surface it’s applied to This level surface also improves paint surface clarity and reduce light scattering, providing improved light reflectance



What is Nanotechnology as it relates to Detailing?



The science of nanotechnology; the creation, organization, or manipulation of materials, devices, or systems at the nanometre level Nanotechnology, Nano particles or Nano structures, exactly what are they and how do they relate to detailing?



Most of these coatings are based around super siloxanes, and not true nanotube/tubule technology. This would cause a serious health concern for all of those - not to mention be ridiculously expensive. The context that “nano" (as related to detailing) is only as a relative size indicator merely to identify a siloxane/polymer.

They are sub micron particles that form a clear thin film of tightly packed nano particles forming an extension of the surface. The particles are up to a 1000 times denser which makes for an ultra durable hard wearing surface.



Technically most detailing product particulates are not nano metre in size, although they are extremely small, as the term ‘nano’ adequately describes. Single-component coatings interlace on a molecular basis and form an extremely durable protective layer on the paint surface provided they are applied properly.



The significance of a nano-coating is its micro sized particles that can form a very tight bond with the surface of most materials; including glass, paint, plastic, rubber, aluminium, chrome, stainless steel and fabrics. These materials will have surface imperfections i.e. peaks and valleys, micro-fissures when viewed under high magnification.



These undulations allow a nano-coating polymer to form a tight molecular bond (much like a printer’s powdered ink when poured over paper that has writing indentations on it) with the surface it’s applied to.




http://i3.photobucket.com/albums/y88/TOGWT/NanoParticles_zps1de5e767.jpg

Formation of a Nano Structure



Sealing a surface with nanotechnology means applying nano-structures onto the surface, these treated surfaces become hydrophobic and resists road dirt, grime and etc attaching to its surface by the ‘Lotus Effect’. It is therefore highly water repellent, which enables less effort during the cleaning stages and optimum protection to the paintwork, glass, alloys, fabric and trim.



Nanotechnology coatings form a very tight matrix chain-link a nano structure that comprises a clear thin film of tightly packed nano particles forming an extension of the surface. These very dense particles are both a very strong bond and one that is not easily breached by chemicals or detergents. They also improve paint surface clarity and reduce light scattering, providing improved light reflectance



Through self-organizing anti adhesion components, the nanostructure forms an invisible barrier similar to glass. They form a bond by lodging themselves into the micro pores of the paint forming an anchored foundation and then this foundation is built upon to form the nano particle matrix.



This is why a clean, dry and oil-free (micro pore) surface is so important. Only the nanostructure remains on the sealed surfaces, while the water evaporates.



Nanotechnology offers superior durability, hydrophobicity, surface hardness and scratch resistance, resistance to environmental contaminants, works like a clear coat in providing ultra violet (UV) and heat radiation protection without colour change (yellowing) or oxidation and easier maintenance, simply rinsing with plain water results in a clean surface without loss of gloss. I think these products will have a profound impact and radically change auto detailing



Paint Surface Preparation (nanotechnology coatings)



The surface cleaning process is absolutely crucial in order to achieve long lasting results. The cleaner your cars’ paint is before the coating is applied, the longer the protective layer will last.



Prepare the paint surface to your personal level of perfection (washed, clayed, decontaminated, polished and an isopropyl alcohol wipe-down process) Polish the paint surface to remove any surface scratches as this product will highlight them



The solvent in most paint protection products (coatings being the exception) will actually displace waxes and oils, allowing the product to bond with the paint surface and cross-link (polymers) or cure (waxes).



However prior to the application of a paint protection coating it is absolutely necessary to remove any (mostly invisible to the naked eye) fillers, oils and other residue, if they are allowed to remain a white or grey hazing will appear on the paint surface once the coating is applied.



Gtechniq Panel Wipe – removes surface residue (silicone, surfactants, oil, wax and polish lubrication residue) allowing a ‘clean’ surface prior to the application of a coating product to effectively form a chemical bonds. Panel Wipe blend pure alcohols with aromatic solvents to dissolve any polish residues and `flash` off, to leave a completely ‘cleaned’ surface prior to the application of a coating paint protection product.



#Nanotechnology Coating products



1. AQuartz is an inorganic silica / silicon dioxide

2. G|techniq is an inorganic silicate crystallization compound

3. Nanolex is an inorganic, solvent-based nanostructure coating

4. DuPont`s SupraShieldâ„¢, PPG`s Optechâ„¢ and CeramiClearâ„¢ are all inorganic silica coating



Bibliography



1. Royal Society of Chemistry (RSC) Library & Information Centre

2. Glossary of Chemical Terms - Faculty of Chemical Technology

3. Basic Concepts of Nanotechnology, History of Nano-Technology, News, Materials and Potential Risks

4. Lotus-inspired nanotechnology applications, B. Karthick1 and Ramesh Maheshwari

5. SpecialChem4 Polymers

6. Macromolecular Chemistry and Physics

7. European Coatings Handbook 2nd Edition, by Brock, Groteklaes, Mischke

8. Bayer Material Science, Automotive eNewsletters (Coating, Adhesives and Specialties)



The information in this article is based on the current status of the technical development as well as our experience with the product.







[Edit: General revision and updates 02.26.13]

imported_Larry A
08-01-2011, 09:08 AM
Eagle One claims that there carnuba wax is Nano-tech. Can Nano -tech be a carnuba as well as polimer?

togwt
08-01-2011, 09:43 AM
Nano and nanotechnology are being used as buzzwords by marketing people who have no idea what nano constitutes (the reason for my post) but use the terminology to make their product sound like new technology.



Wax particulates are generally too large to qualify as nano

White lexus 23
08-01-2011, 10:08 AM
You say it is scratch resistant. But I have heard some people say opti coat can become swriled. Is that true? does that also happen with cquatrz?

Chris@Optimum
08-01-2011, 08:54 PM
Scratch resistance is improved over OEM clear coats, but nothing is scratch "proof". These coatings reduce maintenance effort significantly, but should never be seen as an excuse to cut corners and use sloppy technique that causes marring. Aside from improved hardness, marring is reduced by easier drying (blowdrying is awesome after Opticoat), and less effort to remove dirt and debris (airborne contaminant bonding is greatly reduced).

togwt
08-02-2011, 03:19 AM
As stated nothing is scratch proof (meaning nothing can scratch it), all nano products (inculding CeramiClear) are only scratch resistant, that is to say they will resist scratches up to a pencil hardness i.e 9H (see above article)





So how can a dense (hard) clear coat be so easily scratched?



Force acts through a body that has a surface area; if the surface area is really small while maintaining an equal force, the pressure becomes astronomical and the object under pressure capable of penetrating the surface of an otherwise tough material. (Newton`s third law of motion)



That’s why a micro fine thread that is twice as fine as silk and a 100 times finer than a human hair, in an otherwise soft towel will scratch your paint. And the same reason a mosquito can penetrate a rhino hide with its proboscis (stinger).



This can best be summed up as: your car’s paint finish, though it may feel hard, is actually rather soft. Nearly everything else that comes in contact with it, though it may feel soft, is harder by comparison and will scratch it with enough pressure – sometimes just the slightest of pressure

TTCarrera
01-27-2013, 01:12 PM
Is it safe to use a nano-tech product like the ones in your article on a brand new 2013 Porsche (new paint shop at the Porsche factory, supposedly with state of the art processes)? Went through the paint shop on 1/17/13. When is it fully cured and safe to use one of these products?



Same question, for traditional carnuba wax?



Thanks in advance

togwt
01-27-2013, 06:48 PM
Short anwer Yes



Longer aswer-Original Equipment Manufacturer (OEM) paint is cured at high temperatures; OEM paints are cured in a paint oven at around 320. °F (160. °C) for 20 minutes, in multiple oven zones where the paint is baked with radiation and convection heat, or infrared so that 90-95% of the paint systems out gassing has taken place, the additional 5-10% will cure within 2-3 days, it will probably be stored for one or two days before transportation, it is then shipped or transported OTR to a dealership and most likely be on the lot for a few weeks or more. So the vehicle’s paint can be waxed as soon as you take delivery. Check the door jamb sticker and it will tell you the month and year the car was assembled / painted, most vehicles are anywhere from two weeks to six months before customer delivery.



By not applying some sort of paint protection soon after purchase the customer is actually damaging the paint surface instead of helping it. Salesmen that advise a customer not to wax a car for 3-6 months are relying on old paint methods and are misinformed about the latest paint technology.