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togwt
08-01-2011, 04:30 AM
Water doesn’t leave marks or etch glass; it’s the minerals that it contains calcium (Ca) and magnesium (Mg) and reactivity (heat acting as a catalyst) the spots are actually traces of minerals left on the surface. Alternatively they can be caused by industrial pollution (i.e. acid rain, bird excrement or industrial fallout)



Generally surface water-spots have no raised edges and are very shallow and so cannot be felt, they are very similar to micro-fine surface marring. They cannot be removed from the surface by washing but they can usually be removed with a slightly abrasive chemical paint cleaner



There are two categories of water mark (the so-called water spots)



Stage I (Surface) Corrosion

[: defined as a surface with light to moderate corrosion damage to the paint surface]



Stage II (Sub-surface) Corrosion

[: definition when the dirt/corrosion deposits are no longer on the surface but have started to break down the molecular structure, leaving an etched or white haze on the surface( a concave circular mark ) after the stain has been removed, with moderate to serious paint damage



a) Surface water spots- (Stage I Corrosion) alkaline watermarks consist of calcium (Ca) and magnesium (Mg) both of which are basic (alkaline pH 10) that alight on the surface; ultra violet (heat) radiation (UVR) will leave a white ‘water mark’, the minute crystals bond to the surface, they will not wash off as they are insoluble and if left for any length of time they will etch the paint film surface leaving a concave circular mark, remove surface deposits with detailer’s clay and an acetic acid pH 2.0 (vinegar) to naturalise the alkaline



b) Sub- surface (etched) spots- (Stage II Corrosion ) are caused by an aggressive alkaline or an acidic solution (acid rain, bird excrement or industrial fallout) causing a chemical reaction, if left for any length of time they will etch the paint film surface leaving a concave circular mark. Unlike water spots which typically have a white outline of the spot, acid rain etching is smaller and you can see the damage in the clear coat.



Inspect the surface etching under magnification, and then you will be able to assess the damage. Magnification will allow you to view paint flaws in perfect detail. View the edges of acid rain or water spot damage, and the hard-to-see depth of scratches. Only then, you will be able to assess the real damage. The edge should be levelled, which will make the etched depression almost invisible.

Etched acid rain spots are one of the most difficult paint defects to remove so be patient as it will probably take more than one attempt to remove them.



Acid spots require an abrasive polish to level the surface (some stubborn marks may require wet sanding) and an alkaline solution to neutralize them, simply rinsing a vehicle with deionised water or tap water activates / reactivates the acid concentrates.



If the surface can be rectified by chemical means then this is the answer; not abrasive polishing. Using the correct chemical cleaners will dissolve the contaminants rather than abrading the surface. With all cleaning products (especially solvents) always test a small inconspicuous area first to ensure it won`t discolour, stain or etch the surface, and ensure that the pH of the product is suitable for the material After the paint surface has been subjected to a chemical cleaning its protective layer (s) have been removed and the paint surface left without protection, so it is very important that a polymer and / or Carnauba wax protection be applied immediately



Removing ‘Water spots’



Always start by using the least abrasive product first



• Use a paint surface cleaner (Z-PC Fusion Dual Action Paint Cleaner or Duragloss 501)

• Try to dissolve the alkaline-based, surface/etched mineral water deposits try one or more of the following;

a) Use a 2:1 or stronger solution of distilled water/distilled white vinegar (Acetic acid)



b) Try a 2:1 solution of distilled water/Isopropyl Alcohol (adjust ratio as required)



c) Or equal parts distilled water/distilled white vinegar/Isopropyl alcohol.



• Clean the effected surface with Klasse All-In-One or Zaino Z-PC Fusion Dual Action Paint Cleaner

• Use detailing clay to remove any `hard` surface granules

• Use a machine polish (Optimum Polish, Optimum Compound) and a cutting (LC White, Orange or Yellow) foam pad (speed # 4- 5.0) to level the paint surface

• Use the least aggressive polish/foam pad first, if this doesn’t remove the problem step-up to a more aggressive polish / foam pad set-up

• Wet-sand with 2000, 2500 or 3000 grit finishing paper



a1) Removing surface (Stage I Corrosion) water marks

• Use detailing clay to remove any `hard` surface granules

• Use a surface cleaner (Z-PC Fusion Dual Action Paint Cleaner)

• Dissolve the alkaline-based, surface/etched mineral water deposits try one or more of the following;



a) Use a 2:1 solution of distilled water/distilled white vinegar (Acetic acid pH 2.4)



b) Try 2:1 solution of distilled water/Isopropyl Alcohol (adjust ratio as required)



c) Or equal parts distilled water/distilled white vinegar/Isopropyl alcohol. Allow chemical solution sufficient remain in place time (5-10 minutes)



• Use a clean spray bottle and 100% cotton Micro fibre cloth to apply the solution to the surface

• Or soak a first aid gauze pad with the vinegar/ water solution, this will help it stay in place during the necessary remain in place time, 5-10 minutes) wipe off any residue from surface and dry with a damp waffle weave towel

• Use a clean spray bottle and 100% cotton micro fibre cloth to apply the solution to the surface

• Wipe off any residue from the surface and dry with a damp waffle weave towel

• If any `water marks` remain apply distilled white vinegar or Isopropyl alcohol un-diluted to a 100% cotton micro fibre towel, using a medium/heavy pressure on surface, for stubborn spots use an abrasive polish as in 1b)



b1) Removing etched below surface (Stage II Corrosion) water marks



• These can be removed by using detailer`s clay to remove any hardened surface deposits

• Then using a machine polish ( Optimum Polish, Optimum Compound, Zaino Z-PC Fusion Dual Action

• Paint Cleaner or Klasse All-In-One ) and a cutting (LC Orange or Yellow) foam pad (speed # 4-5.0 / 1200 RPM ) to level the surface (use the least aggressive polish/foam pad first, if this doesn’t remove the problem step-up to a more aggressive set-up)

• Work on a very small area at a time (2-foot x 2-foot) until the polish has run out

• Repeat this process two or three times, as necessary

• Reapply surface (paint) protection once spots have been removed.



If none of the above methods remove the etched water spots consider wet-sanding the paint finish (See also Glass Polishing article)

To neutralise acid water spots using a polish or compound will remove the etching and the indentations, the below paint surface should then be neutralised ValuGard’s A B C Decontamination / Neutralization system



If the surface can be rectified by chemical means then this is the answer; not abrasive polishing. Using the correct chemical cleaners will dissolve the contaminants rather than abrading the surface. With all cleaning products (especially solvents) always test a small inconspicuous area first to ensure it won`t discolour, stain or etch the surface, and ensure that the pH of the product is suitable for the material

After the paint surface has been subjected to a chemical cleaning its protective layer (s) have been removed and the paint surface left without protection, so it is very important that a polymer and / or Carnauba wax protection be applied immediately



Notes-

1. Synthetic steel or bronze wool whatever the grade can leave micro-scratches in the glass, which then become impregnated with road dirt, grit and grime, causing a clouding the glass over time, which impairs visibility.

2. Do not use abrasive cleaner; glass polish or any grade synthetic steel wool on after market-tinted glass or you will probably scratch the surface.

3. For deeply etched water spots (> 0.004 Mil) in the windshield surface, do not attempt to polish them out, consult an automotive windshield vendor as glass or plastic used on later model cars is soft and thin (this may vary by manufacturer) due to weight / cost savings by vehicle manufactures and polishing could cause surface to become badly scratched, stressed or cracked.

4. Be cautious with polishes that contain abrasives like aluminium or cerium oxide as they have the potential to damage glass beyond repair.

5. Some windshields and mirrors have a tinted plastic coating or a blue tint that will scratch or be damaged, only use a glass polish (not synthetic steel or bronze wool) on uncoated glass.

6. Vinegar is a liquid produced from the fermentation of ethanol in a process that yields its key ingredient, Acetic (Ethanoic acid)[/I]






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